Balance the redox reaction in acid solution
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P+Cu2+-->Cu+H2PO4
P in P has oxidation state of 0
P in H2PO4 has oxidation state of +6
So, P in P is oxidised to H2PO4
Cu in Cu+2 has oxidation state of +2
Cu in Cu has oxidation state of 0
So, Cu in Cu+2 is reduced to Cu
Reduction half cell:
Cu+2 + 2e- --> Cu
Oxidation half cell:
P --> H2PO4 + 6e-
Balance number of electrons to be same in both half reactions
Reduction half cell:
3 Cu+2 + 6e- --> 3 Cu
Oxidation half cell:
P --> H2PO4 + 6e-
Lets combine both the reactions.
3 Cu+2 + 1 P --> 3 Cu + 1 H2PO4
Balance Oxygen by adding water
3 Cu+2 + 1 P + 4 H2O --> 3 Cu + 1 H2PO4
Balance Hydrogen by adding H+
3 Cu+2 + 1 P + 4 H2O --> 3 Cu + 1 H2PO4 + 6 H+
This is balanced chemical equation in acidic medium
Answer:
3 Cu2+ + P + 4 H2O --> 3 Cu + H2PO4 + 6 H+
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