For an atom of any elements. What atomic orbitals contain electrons with the highest energy? Excluding Hydrogen.
For any main quantum nuber n, orbitals with quantum number l=n-1 (the last orbital or valence orbital) - contain electrons with the highest energy.
Any electron can be characterized by four quantum numbers - things derived from Schredinger equation solution. Among them, energy of electron described by main (n) quantum number and l (described as 0,1,2 ... n-1) - the highest n, more energy of electron. For example, electrons on the highest level of K - 3s-electron has higher energy than electron of 2p. 3s - the last electron, or valence, it much far rfom nucleus.
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