In the Polymers Lab .... If the same amounts of sebacoyl chloride, 1,6-hexanediamine and sodium hyrdroxide were combined as above, but a solvent was used to afford a homogenous reaction mixture, would the yield of polymer increase, decrease, or remain the same? Explain?
Ans. Sebacoyl chloride immediately reacts with water to from HCl. It reduces the reactivity of sebacoyl chloride towards 1,6-adiamniohexane, thus also reduces formation of product nylon or reduces the yield.
So, the reaction mixture is set up in three different layers in the beaker (reaction vessel)-
Bottom layer (layer 1). Sebacoyl chloride
Middle layer (layer 2) : 1,6-adiamniohexane
Uppermost layer (layer 3): aqueous solution of NaOH. Water with density lower than 1,6-adiamniohexane floats on the middle layer.
This set up maximizes reaction of sebacoyl chloride with 1,6-adiamniohexane forming nylon simultaneously with separating sebacoyl chloride from the aqueous phase.
Carrying the reaction in a solvent that better homogenizes the three layers will reduce the yields because sebacoult chloride reacts with water and no longer be useful to react with 1,6-adiamniohexane .
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