Calculate the concentration of an oxalic acid (H2C2O4) solution if it takes 34.0 mL of a 0.200 M NaOH solution to consume the acid in 25.0 mL of the oxalic acid solution. The net ionic equation of the titration reaction is: H2C2O4(aq) + 2 OH– (aq) --> C2O42–(aq) + 2 H2O(l)
H2C2O4(aq) + 2 OH– (aq) C2O42–(aq) + 2 H2O(l)
Volume of NaOH solution = 34.0 mL
Molarity of NaOH solution = 0.200 M
Milimoles of OH- ions = 34.0 * 0.200
= 6.8
As it can be seen from equation that 2 moles OH- ions are required for titration of 1 mole oxalate ions.
So milimoles of oxalic acid required = 6.8 / 2
= 3.4
Volume of oxalic acid solution = 25.0 mL
molarity of oxalic acid solution = Milimoles / volume
= 3.4 / 25
= 0.136 M
So, the concentration of an oxalic acid = 0.136 M
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