Question

A solution of [Ni(H2O)6]2+ is green and paramagnetic (µ = 2.90 BM), whereas a solution of...

A solution of [Ni(H2O)6]2+ is green and paramagnetic (µ = 2.90 BM), whereas a solution of [Ni(CN)4]2- is colorless and diamagnetic.

Suggest a qualitative explanation for these observations. Include diagrams showing the molecular geometry for each complex. you may draw crystal field diagrams for both molecules to explain the magnetic behavior of these complexes. Be sure to suggest a reason why [Ni(H2O)6]2+ is green and [Ni(CN)4]2- is colorless.

Homework Answers

Know the answer?
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for?
Ask your own homework help question
Similar Questions
Explain the following observations on the basis of the ligand field splitting of the d orbitals....
Explain the following observations on the basis of the ligand field splitting of the d orbitals. Include the properties of the ligands in your explanation. a) The complex [Ni(CN)4]2- is diamagnetic whereas [NiCl4]2- is paramagnetic with two unpaired electrons. b) The octahedral complex [Fe(CN)6]3- has only one unpaired electron whereas the hexaaqua complex [Fe(H2O)6]3+ has five.
Provide a reasonable explanation for the following experimental observations. a) The wavelength of the absorption maximum...
Provide a reasonable explanation for the following experimental observations. a) The wavelength of the absorption maximum in the UV/vis spectra of Cr(III) complexes decreases in the order [CrCl6]3-, [Cr(NH3)6]3+, [Cr(CN)6]3-. b) Low spin Fe(III) complexes have stronger d-d transitions (are more intensely colored) than the corresponding high spin complexes. c) The initial rate of Cl- substitution is 108 times faster for [Fe(H2O)6]2+ (μeff = 5.9 μB) than for [Ru(H2O)6]2+ (μeff = 0 μB) and is independent of the concentration of...
1. Put these complexes in order of increasing rate of substitution by H2O: [Ni(NH3)6]2+, [Co(NH3)6]3+, [Rh(NH3)6]3+...
1. Put these complexes in order of increasing rate of substitution by H2O: [Ni(NH3)6]2+, [Co(NH3)6]3+, [Rh(NH3)6]3+ 2. State the effect of the following changes on the rate of reactions of octahedral Rh(III) complexes. a) Increase in charge of the complex. b) Changing the spectator ligands from NH3 to PPh3. c) Changing the entering group from Cl- to I-.
I have provided the information for the lab below. I want to see the chemical reactions...
I have provided the information for the lab below. I want to see the chemical reactions that take place during each step of the experiment. So in the procedures when a chemical was added i would like to see what the products and byproducts that were formed. I also want to see one over all reaction for this experiment to just get an overview of what exactly is happening during the experiment. Thank you:) Part B: Synthesis of [Co(NH3)5Cl]Cl2 Objective:...
ADVERTISEMENT
Need Online Homework Help?

Get Answers For Free
Most questions answered within 1 hours.

Ask a Question
ADVERTISEMENT