The following mechanism has been proposed for the gas-phase reaction of chloroform (CHCl3) and chlorine.
Cl2 ? 2Cl (fast, reversible)
Cl + CHCl3 ? HCl + CCl3 (slow)
Cl + CCl3 ? CCl4 (fast)
What rate law does this mechanism predict? (Choose from the list below and enter your answers in alphabetical order, e.g. ABC ).
A)k | G) [HCl]1/2 | M) [Cl]2 |
B) [HCl] | H) [Cl2]1/2 | N) [CHCl3]2 |
C) [Cl2] | I) [Cl]1/2 | O) [CCl3]2 |
D) [Cl] | J) [CHCl3]1/2 | P) [HCl]2 |
E) [CHCl3] | K) [CCl3]1/2 | |
F) [CCl3] | L) [Cl2]2 |
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