Silver chloride is only slightly soluble in pure water at 25∘C:AgCl(s)⇌Ag+(aq)+Cl−(aq)K=1.8×10−10Calculate the concentration of Ag+ and Cl−in a solution that is saturated with AgCl (i.e., the system is at equilibrium and there is still solid AgCl visible).
Ans . For the reaction at 25C AgCl(s)⇌Ag+(aq)+Cl−(aq) ,there exists an equilibrium between the undissolved solid and ions i.e.( Ag+(aq) and Cl- (aq) ) in solution. The equilibrium expression can be written:
Kc = ( [Ag+] [Cl¯] ) / [AgCl]
The solid AgCl term in the denominator is actually constant being in the solid state and thus the expression can be written as :
Kc [AgCl] = [Ag+] [Cl¯]
Since Kc [AgCl] is a constant , the modified expression becomes Ksp = [Ag+] [Cl¯]
Given : Ksp = 1.8 * 10-10 = s2 .
s = (1.8 * 10-10)0.5 = 1.341 * 10-5 M.
Thus the concentration of Ag+ and Cl- = 1.341 * 10-5 M at equilibrium conditions.
Get Answers For Free
Most questions answered within 1 hours.