Question

KD = (Solubility in organic solution (g/mL))/(Solubility in aqueous solution (g/mL) ) , and KD for...

KD = (Solubility in organic solution (g/mL))/(Solubility in aqueous solution (g/mL) ) , and KD for caffeine in a water/dichloromethane system is 7.8. If 5.0 g of caffeine is dissolved in 100 mL of water, how many extractions using 50 mL of dichloromethane are required to recover 95% of the caffeine from the water?

Homework Answers

Know the answer?
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for?
Ask your own homework help question
Similar Questions
5. Consider a 0.3 L aqueous solution that contains 2.6 g of caffeine. The solubility of...
5. Consider a 0.3 L aqueous solution that contains 2.6 g of caffeine. The solubility of caffeine in water is 2.2 g/100 mL and the solubility in methylene chloride is 10.2 g/100 mL. a) How much caffeine can be extracted with 70 mL of methylene chloride? b) How much caffeine will be extracted if the aqueous solution is extracted twice with 30 mL of methylene chloride? c) Which is more effective a or b?
Assume that the solubility of caffeine in water is 4.0 g/100 mL and in methylene chloride...
Assume that the solubility of caffeine in water is 4.0 g/100 mL and in methylene chloride it is 16.0 g/100 mL at 25°C. What is KD for this system?
The distribution coefficient for caffeine in dichloromethane and water is 4.6 a. Assume that 0.100 g...
The distribution coefficient for caffeine in dichloromethane and water is 4.6 a. Assume that 0.100 g of caffeine are dissolved in 15 mL of water. The aqueous layer is extracted twice with 15 mL of dichloromethane. How much caffeine may be recovered from this extraction? b. Would the previous extraction be more efficient if the aqueous solution of caffeine (0.100 g dissolved in 15 mL of water) was extracted once with 30 mL of dichloromethane instead? Please provide step by...
Suppose a reaction mixture, when diluted with water, afforded 300 mL of an aqueous solution of...
Suppose a reaction mixture, when diluted with water, afforded 300 mL of an aqueous solution of 30 g of the reaction product malononitrile [CH3(CN)2]], which is to be isolated by extraction with ether. The solubility of malononitrile in ether at room temperature is 20.0 g/100 mL, and in water is 13.3 g/100 mL. Keeping in mind that Kd is the ratio of solubilities in the two solvents what weight of malononitrile would be recovered by extraction by a 100-mL portion...
consider a 0.3L aqueous solution contains 2.6g of caffeine. the solubility of caffeine in water is...
consider a 0.3L aqueous solution contains 2.6g of caffeine. the solubility of caffeine in water is 2.2g/100ml and the solubility in methylene chloride is 10.2g/100ml. a) How much caffeine can be extracted with 70ml of methylene chloride? b) How much caffeine will be extracted if the aqueous solution is extracted twice with 30ml of Methylene chloride c) Which is more effective, a or b?
.102 g pure caffeine is added to .1 mL methylene chloride and .1 mL water, shaken...
.102 g pure caffeine is added to .1 mL methylene chloride and .1 mL water, shaken and allowed to separate. the water is removed and the remaining liquid is mixed with sodium sulfate. This is dry filtered with an additional .5 mL water into a flask. The remaining liquid is heated, leaving the solid behind. What is the caffeine's theoretical yield? Density of CH2Cl2 is 1.3255. Also, I started by finding by the KD = solubility in organic solvent (g/100mL)...
Organic compound with partition coefficient of 7.54. If there are initially 6.67 g of the compound...
Organic compound with partition coefficient of 7.54. If there are initially 6.67 g of the compound dissolved in 70.0 ml of water, how many g will remain in aqueous layer after extraction with 30.0 ml of ether?
The solubility of CaCl2 in water at 25°C is 81.1 g/100 mL; at 0°C its solubility...
The solubility of CaCl2 in water at 25°C is 81.1 g/100 mL; at 0°C its solubility decreases to 59.5 g/100 mL. Answer the following questions about an aqueous solution of 26.4 g of CaCl2 in a volume of 37.5 mL: a. At 25°C, is this a saturated solution? b. If the solution is cooled to 0°C, do you expect a precipitate to form? c. If the solution is slowly cooled to 0°C and no precipitate forms, then what kind of...
An organic compound A has the following solubilities at room temperature: 12 g A in 100...
An organic compound A has the following solubilities at room temperature: 12 g A in 100 mL ether; 6 g A in 100 mL H2O ( K = 2). Calculate which of the following extraction methods will yield the largest mass of A. Include masses of the compound yielded in both extractions. Method 1: A solution of 6 g of A in 100 mL H2O is shaken with 100 mL ether (one extraction) Method 2: A solution of 6 g...
1. What is the purpose of crystallization in an organic chemistry procedure? 2. Using the solubility...
1. What is the purpose of crystallization in an organic chemistry procedure? 2. Using the solubility data you found for benzoic acid, calculate the volume of water required to dissolve 1.0 g of benzoic acid at room temperature. Calculate the volume of boiling water needed to dissolve 1.0 g of benzoic acid. 3. Explain why a Büchner or Hirsh funnel is used to isolate the final crystallized product instead of stem funnel. 4. Explain when a mixture of solvents would...