Calculate the hydronium ion concentration and the pH of the solution that results when 28.5 mL of 0.16 M acetic acid, HCH3CO2H (Ka= 1.8x10-5), is mixed with 1.3 mL of 0.26 M NaOH
Hydronium ion concentration = _______ M
pH = _____
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milimoles of CH3COOH = 4.56 [ by formula Molarity =no of moles / volume ]
milimoles of NaOH = 0.338 [ since volume is in mL milimoles will come if volume would be in L
pKa = -logKa then only moles will come]
= -log(1.8*10-5)
= 4.74
[Acetic acid is weak acid and NaOH os strong base so NaOH will dissociate completely and Acetic acid will dissociate partially]
Initial conc 4.56 0.338 0 0
After salt formation 4.22 0 0.338 0
pH = pKa +log[salt] / [acid]
= 4.74 + log 0.338 / 4.22
= 4.74 -1.096
= 3.644
[H3O+] = 10-pH
= 10-3.64
= 2.29 * 10 -4 M
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