how many milliliter of 2.0M HCl are required to react with 4.40g of solid containing 26.13wt% Ba(NO3)2 if the reaction is
Ba^2+(aq)+ 2Cl-(aq)-->BaCl2(aq)
mass of Ba(NO3)2 = 26.13 % of sample mass
= 26.13 % of 4.40 g
= 26.13*4.40/100
= 1.15 g
Molar mass of Ba(NO3)2,
MM = 1*MM(Ba) + 2*MM(N) + 6*MM(O)
= 1*137.3 + 2*14.01 + 6*16.0
= 261.32 g/mol
mass(Ba(NO3)2)= 1.15 g
number of mol of Ba(NO3)2,
n = mass of Ba(NO3)2/molar mass of Ba(NO3)2
=(1.15 g)/(261.32 g/mol)
= 4.401*10^-3 mol
So,
mol of Ba2+ = 4.401*10^-3 mol
from reaction ,
mol of HCl = 2*mol of Ba2+
= 2*4.401*10^-3 mol
= 8.802*10^-3 mol
now use:
mol(HCl) = M(HCl)*V(HCl)
8.802*10^-3 = 2.0 M * V
V= 4.40*10^-3 mL
V= 4.40 mL
Answer: 4.40 mL
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