When the following oxidation
0 +2 +1 0
Rb(s) + Cu2+(aq) Rb+(aq) + Cu(s)
Oxidation half reaction : Rb(s) Rb+(aq)
Reduction half reaction : Cu2+(aq) Cu(s)
Balancing oxidation half reaction : Rb(s) Rb+(aq)
Balancing charge ( by adding electrons ) : Rb(s) Rb+(aq) + e- ---------------(1)
Balancing oxidation half reaction : Cu2+(aq) Cu(s)
Balancing charge ( by adding electrons ) : Cu2+(aq) + 2e- Cu(s) ---------------(2)
Add both the equations (1) & (2) so that the electrons on both sides will cancel each other.
This can be done by [2xEqn(1) ] + Eqn (2) gives
2Rb(s) + Cu2+(aq) + 2e- 2Rb+(aq) + 2e- + Cu(s)
2Rb(s) + Cu2+(aq) 2Rb+(aq) + Cu(s)
This is the balanced equation.
So the lowest whole-number coefficient for Rb+(aq) is 2.
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