Question

Phosphorous forms an oxychloride of formula POCl3. Which transition metal is likely to form an oxychloride...

Phosphorous forms an oxychloride of formula POCl3. Which transition metal is likely to form an oxychloride of matching formula?

A.

VOCl3

B.

GeOCl3

C.

GaOCl3

D.

CrOCl3

Homework Answers

Answer #1

P has 5 valence electrons and hence it forms 5 bonds

[Double bond with O and single bond with each Cl]

V has 5 valence electrons (3 in d orbital and 2 in s orbital). So, it can form similar compound

Ge has 4 valence electrons (2 in p orbital and 2 in s orbital). So, it can’t form similar compound

Ga has 3 valence electrons (2 in p orbital and 1 in s orbital). So, it can’t form similar compound

Cr has 6 valence electrons (2 in p orbital and 4 in d orbital). So, it can’t form similar compound

Answer: A

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