Phosphorous forms an oxychloride of formula POCl3. Which transition metal is likely to form an oxychloride of matching formula?
A. |
VOCl3 |
|
B. |
GeOCl3 |
|
C. |
GaOCl3 |
|
D. |
CrOCl3 |
P has 5 valence electrons and hence it forms 5 bonds
[Double bond with O and single bond with each Cl]
V has 5 valence electrons (3 in d orbital and 2 in s orbital). So, it can form similar compound
Ge has 4 valence electrons (2 in p orbital and 2 in s orbital). So, it can’t form similar compound
Ga has 3 valence electrons (2 in p orbital and 1 in s orbital). So, it can’t form similar compound
Cr has 6 valence electrons (2 in p orbital and 4 in d orbital). So, it can’t form similar compound
Answer: A
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