Calculate the number of pounds of CO2 released into the atmosphere when a 21.0-gallon tank of gasoline is burned in an automobile engine. Assume that gasoline is primarily octane, C8H18, and that the density of gasoline is 0.692 g·mL–1 (this assumption ignores additives). Also assume complete combustion.
we know that
1 gallon = 3785.41 ml
so
volume of gasoline = 21 x 3785.41
volume of gasoline = 79493.61 ml
now
we know that
mass = density x volume
so
mass of gasoline = 0.692 x 79493.61
mass of gasoline = 55009.578 g
now
we know that
moles = mass / molar mass
also
molar mass of C8H18 = 114
so
moles of C8H18 = 55009.578 / 114 = 482.54
now
the combustion reaction is
C8H18 + excess 02 ---> 8 C02 + 9H20
we can see that
moles of C02 = 8 x moles of C8H18
so
moles of C02 = 8 x 482.54 = 3860.32
now
mass = moles x molar mass
so
mass of C02 = 3860.32 x 44 = 169854 g
we know that
1 g = 0.00220462 pound
so
mass of C02 = 169854 x 0.0020462 = 374.464
so
374.464 pounds of C02 is produced
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