Question

Give the oxidation state and d-electron count of the metal for the following complexes: a.) [IrCl(CO)(PPh3)2],...

Give the oxidation state and d-electron count of the metal for the following complexes:

a.) [IrCl(CO)(PPh3)2], Vaska’s complex

b.) [(H3C)4Os≡N] ̄

c.) [O=V(OH2)5]2+

For each of the following complexes, give the CFSE and the number of unpaired electrons expected:

a.) [V(CO)6]

b.) [Ru(bipy)3]3+

c.) [CuCl4]2- (tetrahedral)

d.) [CoCl6]3–

e.) [Co(CN)6]3–

Science   Chemistry   
0 0
Add a commentTranscribed image text
Next >

Homework Answers

Answer #1

0 0
Know the answer?
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Log In

Sign Up

Not the answer you're looking for?
Ask your own homework help question
Similar Questions
For the following complexes provide: the name, the d electron count, the metal oxidation state, list...
For the following complexes provide: the name, the d electron count, the metal oxidation state, list what type of isomerism is observed in the given compounds (e.g., cis/trans), and draw the structure. If isomers are possible, you need to draw only one structure. a) Fe(PPh3)3Cl3 where PPh3 = triphenylphosphine. Denote PPh3 in your as PR3. b) K[V(NH3)4Cl2] c) [Mn(en)3] I2 where en = ethylenediamine
9. Count the valence electrons on the central metal in the following complexes. Which obey the...
9. Count the valence electrons on the central metal in the following complexes. Which obey the 18 electron rule?   Fe(CO)4(PEt3), Ta(h5-C5H5)2Cl3, [Rh(bipy)2Cl]+, [Ni(CO)4]2-, cis-[PtCl2(NH3)2], trans-[IrCl(CO)(PPh3)2]  
Determine the oxidation state of the metal ion in [Co(NH3)5Br]2+ Determine the coordination number of the...
Determine the oxidation state of the metal ion in [Co(NH3)5Br]2+ Determine the coordination number of the metal ion in [Co(NH3)5Br]2+. Determine the oxidation state of the metal ion in [Fe(CN)6]4?. Determine the coordination number of the metal ion in [Fe(CN)6]4?. Determine the oxidation state of the metal ion in [Co(ox)3]4?. Determine the coordination number of the metal ion in [Co(ox)3]4?.
Determine the Oxidation State and the Coordination Number of the Transition Metal Ion in each of...
Determine the Oxidation State and the Coordination Number of the Transition Metal Ion in each of the following Complex Ions: a) Ni(H2O)6^ 2+ b) Mn(CN)6 ^4- c) CuCl4 ^2- d) Cr(NH3)6 ^3+
Rationlize the rate constant trends for the following electron transfer complexes (i.e. why is there such...
Rationlize the rate constant trends for the following electron transfer complexes (i.e. why is there such a big difference between 1 and 2 and a big difference between 2 and 3 ? # Reaction pair Rate Constant 1 [Ru(bpy)3]3+/2+ 4 x 108 2 [Ru(NH3)6]3+/2+ 6.6 x 103 3 [Co(NH3)6]3+/2+ 6 x 10-6
Predict whether the molecule is inert or labile. Show reasoning. a. [V(OH2)6]2+ b. [Mn(OH2)6]2+ c. [Fe(CN)6]4–...
Predict whether the molecule is inert or labile. Show reasoning. a. [V(OH2)6]2+ b. [Mn(OH2)6]2+ c. [Fe(CN)6]4– d. [Ru(bipy)3]2+ bipy = 2,2’-bipyridine
1. Put these complexes in order of increasing rate of substitution by H2O: [Ni(NH3)6]2+, [Co(NH3)6]3+, [Rh(NH3)6]3+...
1. Put these complexes in order of increasing rate of substitution by H2O: [Ni(NH3)6]2+, [Co(NH3)6]3+, [Rh(NH3)6]3+ 2. State the effect of the following changes on the rate of reactions of octahedral Rh(III) complexes. a) Increase in charge of the complex. b) Changing the spectator ligands from NH3 to PPh3. c) Changing the entering group from Cl- to I-.
Which one of the following metal complex ions has three unpaired electrons? A) [Mn(H2O)6]2+ (high spin)...
Which one of the following metal complex ions has three unpaired electrons? A) [Mn(H2O)6]2+ (high spin) B) [CoCl6]4?(high spin) C) [MnF6]4? (high spin) D) [Co(NH3)6]2+ (low spin) E) [Mn(en)3]2+ (low spin)
Provide a reasonable explanation for the following experimental observations. a) The wavelength of the absorption maximum...
Provide a reasonable explanation for the following experimental observations. a) The wavelength of the absorption maximum in the UV/vis spectra of Cr(III) complexes decreases in the order [CrCl6]3-, [Cr(NH3)6]3+, [Cr(CN)6]3-. b) Low spin Fe(III) complexes have stronger d-d transitions (are more intensely colored) than the corresponding high spin complexes. c) The initial rate of Cl- substitution is 108 times faster for [Fe(H2O)6]2+ (μeff = 5.9 μB) than for [Ru(H2O)6]2+ (μeff = 0 μB) and is independent of the concentration of...
Draw the crystal-field energy level diagrams and place d-electrons for the following: A) [Cr(H2O)6]2+ (4 unpaired...
Draw the crystal-field energy level diagrams and place d-electrons for the following: A) [Cr(H2O)6]2+ (4 unpaired electrons) B) [Mn(H2O)6]2+ (high spin) C) [Ru(NH3)5(H2O)]2+ (low spin) D) [IrCl6]2+ (low spin) E) [Cr(en)3]3+ F) [NiF6]4-
ADVERTISEMENT
Need Online Homework Help?

Get Answers For Free
Most questions answered within 1 hours.

Ask a Question
ADVERTISEMENT