Question

Give the oxidation state and d-electron count of the metal for the following complexes: a.) [IrCl(CO)(PPh3)2],...

Give the oxidation state and d-electron count of the metal for the following complexes:

a.) [IrCl(CO)(PPh3)2], Vaska’s complex

b.) [(H3C)4Os≡N] ̄

c.) [O=V(OH2)5]2+

For each of the following complexes, give the CFSE and the number of unpaired electrons expected:

a.) [V(CO)6]

b.) [Ru(bipy)3]3+

c.) [CuCl4]2- (tetrahedral)

d.) [CoCl6]3–

e.) [Co(CN)6]3–

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