1.) predict the products of the reaction between the following:
1-chloro-1-methyl cyclohexane and KOH in ethanol
Chlorocyclopentane and sodium ethoxide in methanol
2.) a 1.20g sample of cocaine [alpha]D=-16 was dissolved in 7.50 mL of chloroform and place in a polarimeter sample cell.( path length is 5 cm) What was the observed rotation? Show calculations
3.) draw the transition state structure of the E2 reaction between menthyl chloride and sodium and ethoxide
part -2
where α is the observed rotation
c = concentration in g/ml = 1.20g / 7.50 ml = 0.16 g/ml
l = is the path length in decimeters given 5 cm convert in to diameters = 0.5dm
put all these values in the above equation
-16 = α / 0.16 x 0.5
α = -1.28º
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