Question

The lead-containing reactant(s) consumed during recharging of a lead storage battery is/are Pb(s) only PbO2(s) only...

The lead-containing reactant(s) consumed during recharging of a lead storage battery is/are

Pb(s) only
PbO2(s) only
PbSO4(s) only
both PbO2(s) and PbSO4(s)

both Pb(s) and PbO2(s)

THE ANSWER IS PbSO4(s) only ....BUT WHY, PLEASE GO INTO DETAIL.

Corrosion of iron is retarded by

the presence of salts
high pH conditions
low pH conditions
both the presence of salts and high pH conditions

both the presence of salts and low pH conditions

THE ANSWER IS high pH conditions PLEASE GO INTO DETAIL

What current (in A) is required to plate out 1.22 g of nickel from a solution of Ni2+ in 1.0 hour?

65.4
4.01 x 103
1.11
12.9

2.34

THE ANSWER IS 1.11 PLEASE GO INTO DETAIL

Homework Answers

Answer #1

PbSO4 (s) + H+ + 2e- ------> Pb(s) + HSo4- at cathode

PbSo4 + 2H2O --------> Pb(s) + PbO2(s) + 3H+ (aq) + HSO4- (aq) + 2e-    at anode

--------------------------------------------------------------------------------------------

2PbSo4 + 2H2O --------> Pb(s) + PbO2(s) + 2H+ (aq) + 2HSO4- (aq) rechare the battery

PbSO4(s) only >>>> answer

corrosion of iron at high pH conditions.

The electrochemical corrosion is considered as the anodic dissolution as the anodic of the metal undergoes corrosion.

W = MCt/ZF

   Ni+2 + 2e- -------> Ni

           Z = 2

            F= 96500c

   t = 60*60 = 3600sec

1.22 = 58.67*C*3600/2*96500

C = 1.22*2*96500/58.67*3600   = 1.11A

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