The lead-containing reactant(s) consumed during recharging of a lead storage battery is/are
Pb(s) only | |||||||||||||||||||||
PbO2(s) only | |||||||||||||||||||||
PbSO4(s) only | |||||||||||||||||||||
both PbO2(s) and PbSO4(s) | |||||||||||||||||||||
both Pb(s) and PbO2(s) THE ANSWER IS PbSO4(s) only ....BUT WHY, PLEASE GO INTO DETAIL. Corrosion of iron is retarded by
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PbSO4 (s) + H+ + 2e- ------> Pb(s) + HSo4- at cathode
PbSo4 + 2H2O --------> Pb(s) + PbO2(s) + 3H+ (aq) + HSO4- (aq) + 2e- at anode
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2PbSo4 + 2H2O --------> Pb(s) + PbO2(s) + 2H+ (aq) + 2HSO4- (aq) rechare the battery
PbSO4(s) only >>>> answer
corrosion of iron at high pH conditions.
The electrochemical corrosion is considered as the anodic dissolution as the anodic of the metal undergoes corrosion.
W = MCt/ZF
Ni+2 + 2e- -------> Ni
Z = 2
F= 96500c
t = 60*60 = 3600sec
1.22 = 58.67*C*3600/2*96500
C = 1.22*2*96500/58.67*3600 = 1.11A
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