A 1.85−L vessel contains 4.60 g of a gas at 1.00 atm and 27.0°C. (a) Calculate the density of the gas in g/L. (b) What is the molar mass of the gas?
a) PV = nRT
where, P = pressure = 1.00 atm
V = volume = 1.85 L
n = number of moles
R = Gas constant
T = temperature = 27.0 + 273 = 300 K
1.00 * 1.85 = n * 0.0821 * 300
1.85 = n * 24.6
n = 1.85 / 24.6 = 0.0752 mole
number of moles = mass / molar mass
0.0752 mole = 4.60 g / molar mass
molar mass = 4.60 g / 0.0752 mol = 61.2 g/mol
Therefore, molar mass of gas = 61.2 g/mol
b) P * molar mass = density * R * T
1.00 * 61.2 = density * 0.0821 * 300
61.2 = denisty * 24.6
denisty = 61.2 / 24.6 = 2.49 g/L
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