Question

Suppose you are performing an experiment that requires a constant pH of 9.00. 1) Which buffer...

Suppose you are performing an experiment that requires a constant pH of 9.00.

1) Which buffer system would be most appropriate? HOBr−NaOBr or HOCl−NaOCl? Ka for HOBr is 2.0×10−9, Ka for HOCl is 3.5×10−8.

For this question, the appropiate buffer is HOBR-NaOBr, though I'm not sure why.

2) Calculate the ratio of conjugate base to weak acid required to prepare a buffer with pH= 9.00.

I tried using the Henderson-Hasselbach equation for this but came up with the wrong answer according to my online homework. Any help would be appreciated!

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