Question

Use Hess's Law to calculate the enthalpy change for recovering tungsten from its oxide using the...

Use Hess's Law to calculate the enthalpy change for recovering tungsten from its oxide using the reaction:WO3(s) + 3H2(g) --> W(s)+3H2O(g)

from the following data :

2W(s)+ 3O2(g)-->2WO3(s) , change in H = -1685.4 kJ

2H2(g)+O2(g)---> 2H2O(g) , change in H = -477.84 kJ

Homework Answers

Answer #1

Target reaction :   WO3(s) + 3H2(g) --------> W(s)+3H2O(g)

Given reactions :

2W(s)+ 3O2(g)-->2WO3(s) , change in H = -1685.4 kJ      Reaction1

2H2(g)+O2(g)---> 2H2O(g) , change in H = -477.84 kJ    reaction2

so carrying out the algebraic operations on the given reactions to get the target reaction.

-1/2(Reaction1 ) + 3/2( reaction2 ) = target reaction

so Enthapy of target reaction = -1/2( -1685.4 kJ) + 3/2(-477.84 kJ )

                                             = 842.7 + ( -716.76 ) = 125.94 KJ

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