Lead (Pb) exists as four naturally occuring isotopes: 204Pb, 206Pb, 207Pb, and 208Pb. Using the data from the table below, calculate the atomic mass of 208Pb.
Isotope | Atomic Mass (amu) | Natural Abundance (%) |
204Pb | 203.973 | 1.4 |
206Pb | 205.974 | 24.1 |
207Pb | 206.976 | 22.1 |
208Pb | ? | ? |
Average Atomic Mass | 207.2 amu | 100 |
Given:
m1 = 203.973 amu
A1 = 1.4 %
m2 = 205.974 amu
A2 = 24.1 %
m3 = 206.976 amu
A3 = 22.1 %
m4 = 206.976 amu
A4 = 100 - A1 - A2 - A3
= 100 - 1.4 - 24.1 - 22.1
= 52.4 %
A = 207.2 amu
use:
atomic mass = sum of (mass of isotope * abundance) / 100
A = (m1*A1 + m2*A2 + m3*A3 + m4*A4)/100
207.2 = (203.973*1.4 + 205.974*24.1 + 206.976*22.1 + m4* 52.4)/100
207.2*100 = (203.973*1.4 + 205.974*24.1 + 206.976*22.1 + m4* 52.4)
20720 = (9823.70 + m4* 52.4)
m4* 52.4 = 10896.3
m4 = 10896.3 / 52.4
m4 = 207.945 amu
Answer: 207.945 amu
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