Question

the overall formation constant for Ag(CN)2- equals 5.3 x 10 18, and the Ksp for AgCN...

the overall formation constant for Ag(CN)2- equals 5.3 x 10 18, and the Ksp for AgCN equals 6.0 x 10-17. Calculate Kc for AgCN(s) +CN- makes Ag(CN)2

Homework Answers

Answer #1

Ag^+ (aq) + 2CN^- (aq) -------------> [Ag(CN)2]^-      Kf = 5.3*10^18

Kf   = [Ag(CN)2]^- /[Ag^+][CN^-]^2

AgCN(s) --------------> Ag^+(aq) + CN^- (aq)               Ksp = 6*10^-17

Ksp   = [Ag^+][CN^-]

Kf *Ksp   = [Ag(CN)2]^- /[Ag^+][CN^-]^2 * [Ag^+][CN^-]

                 = [Ag(CN)2]^- /[CN^-]

Kf*Ksp     = kc

5.3*10^18 *6*10^-17   = kc

kc   = 318>>>>>answer

Kc for AgCN(s) +CN- -------> Ag(CN)2 is 318 >>>>>answer

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