Given:
Ka of HClO4 = 3.0 E-8
[HClO4] = 0.015 M
By using reaction with HClO4 with H2O and ICE we can get ionized moles of acid.
ICE
HClO4 (aq) + H2O---- > ClO4- (aq) + H3O+ (aq)
I 0.015 0 0
C -x +x +x
E (0.015-x) x x
Now we use ka expression
ka = [H3O+][ClO4-] / [HClO4]
3.0 -8 = x2 / (0.015-x)
Since the value of ka is very small that we can neglect the value of x in the bracket.
3.0 -8 = x2 / 0.015
x = 2.12 E-5
we can see that x is the amount of mole ionized from acid.
So the percent ionization = (concentration of ionized ions / Initial concentration of acid )x 100
=(2.12E-5 / 0.015 ) x 100
=0.14 %
So the percent ionization = 0.14 %
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