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Calculate the crystal field stabilization energy in terms of Δt and pairing energy (P) for a...

Calculate the crystal field stabilization energy in terms of Δt and pairing energy (P) for a high spin Ni2+ ion in a tetrahedral complex.

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Answer #1

Ni2+ is a d10   system  

thus in tetrahedral complex     its    electronic configuration is     e 4    t26

so crystal field stabilization energy =( -0.6 x e 4   electrons + 0.4 x t26   electrons) + 5p

                                                                = 0Δt + 5p

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