Thioglycolic acid, a substance used in depilatory agesnt has pKa=3.42. What is the percent dissociation of thioglycolic acid in a buffer solution at pH=3.0? Please offer a good explanation!
calculate the ka value from pKa
ka = 10-pKa = 10-3.42 = 3.8 x 10-4
Thioglycolic acid is a HSCH2COOH it is a week acid
with a given information we can find out the concentration
pH = 1/2 (pKa-logC)
where C is the concentration of thioglcolic acid
3.0 = 1/2 (3.42 - logC)
logC = 3.42-6
logC = -2.58
C = 10-2.58
C = 0.00263M
now construct the ICE table
HSCH2COOH <-----------> HSCH2COO- + H+
I 0.00263 0 0
C -x +x +x
E 0.00263-x +x +x
Ka = [H+][HSCH2COO-] / [HSCH2COOH]
3.8 x 10-4 = [x][x] /[0.00263-x]
x2 + x3.8 x 10-4 -9.9 x 10-7 =0
solve the quadratic equation
x = 0.000827 M= [H+]
now percentage of ionisation = (concentration of H+ / concemtration of Thioglycolic acid) x 100
= (0.000827M / 0.00263M) x 100
= 31.44 %
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