An excited hydrogen atom emits light with a wavelength of 397.2
nm to reach the
energy level for which n = 2. In which principal quantum level did
the electron
begin? (c = 3.00 x 108 m/s, h = 6.63 x 10-34 J•s, RH = 2.18 x
10-18J).
According to Rydberg equation
= RH × ( - )
given, = 397.2 nm = 397.2 ×10-9 m .
ni = 2
RH = 2.18×10-18 J = ( 2.18×10-18 × ) m-1
= 2.18×10-18 × m-1
= 1.096 ×107 m-1 .
so,
= 1.096 × 107 ( - )
or, ( - ) =
or, = ( - 0.2296 )
or, = 0.0205
or, nf2 = 49
or, nf = 7.
Hence, the electron began at principal quantum number 7.
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