An optically pure sample of R-C6H5CHClCH3 with a specific rotation of -190 was converterted into the corresponding alcohol via SN1 reaction. The specific rotation of optically pure R-C6H5CHOHCH3 is -42.3 What is the specific rotation of the product? The answer is NOT -42.3 Please Explain why, because I am lost
An optically pure sample of R-C6H5CHClCH3 with a specific
rotation of -190 was converterted into the corresponding alcohol
via SN1 reaction. So the product of the SN1 reaction reaction will
be a raceimic mixture containg both R-C6H5CHOHCH3
and S-C6H5CHOHCH3.
R-C6H5CHClCH3 -------------> R-C6H5CHOHCH3 +
S-C6H5CHOHCH3. (SN1)
The specific rotation of optically pure R-C6H5CHOHCH3 is
-42.3
So, the specific rotation of optically pure S-C6H5CHOHCH3 will be
+42.3.
Hence, the specific rotation of the product i.e raceimic
mixture will be zero (0).
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