A mixture of 60.0 g of S and 1.02×102 g of Cl2 reacts completely to form S2Cl2 and SCl2. Find the mass of S2Cl2 formed.
the reaction is
3S + 2Cl2 --> S2Cl2 + SCl2
we know that
moles = mass / molar mass
so
moles of S = 60 / 32 = 1.875
moles of Cl2 = 102 / 71 = 1.437
now
from the reaction
moles of S required = 1.5 x moles of Cl2
moles of S required = 1.5 x 1.437 = 2.155
but
only 1.875 moles of S is present
so
S is the limiting reagent
now
moles of S2Cl2 formed = (1/3) x moles of S
= 1.875 / 3
= 0.625
now
mass = moles x molar mass
soo
mass of S2Cl2 formed = 0.625 x 135
mass of S2Cl2 formed = 84.375
so
84.375 grams of S2Cl2 is formed
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