Question

Derive an expression for the isothermal reversible expansion of a van der Waals gas. Account physically...

Derive an expression for the isothermal reversible expansion of a van der Waals gas. Account physically for the way in which the coefficients a and b appear in the expression. Using Maple, plot the expression along with that for an ideal gas. For the van der Waals gas, use a case first where a = 0 and b = 5.11 x 10-2 mol-1 and where a = 4.2 L2 atm mol-2 and b = 0. Take Vi = 1.0 L, Vf = 2.0 L, n = 1.0 mol, and T = 298 K.

Homework Answers

Know the answer?
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for?
Ask your own homework help question
Similar Questions
7. 1.55 moles of Argon gas undergo an isothermal reversible expansion from an initial volume of...
7. 1.55 moles of Argon gas undergo an isothermal reversible expansion from an initial volume of 5.00 L to 105. L at 300 K. Calculate the work done during this process using: (a) the ideal gas equation, and (b) the van der Waals equation of state. Van der Waals parameters for Ar are available in the back of the book. Compare the two results, what percentage of the work done by the van der Waals gas arises due to having...
Use the van der Waals equation and the ideal gas equation to calculate the pressure for...
Use the van der Waals equation and the ideal gas equation to calculate the pressure for 2.00 mol He gas in a 1.00 L container at 300.0 K. 1st attempt Part 1 (5 points) Ideal gas law pressure_____ atm Part 2 (5 points) Van der Waals pressure_____ atm
Use the ideal gas equation and the Van der Waals equation to calculate the pressure exerted...
Use the ideal gas equation and the Van der Waals equation to calculate the pressure exerted by 1.00 mole of Argon at a volume of 1.31 L at 426 K. The van der Waals parameters a and b for Argon are 1.355 bar*dm6*mol-2 and 0.0320 dm3*mol-1, respectively. Is the attractive or repulsive portion of the potential dominant under these conditions?
The amount n = 2.00 mol of a van der Waals gas with a = 0.245...
The amount n = 2.00 mol of a van der Waals gas with a = 0.245 m6 Pa mol-2 occupies a volume of 0.840 L if the gas is at a temperature of 85.0 K and at a pressure of 2850 kPa. From this information, calculate the van der Waals constant b and the pressure p of this gas sample when it occupies a volume of 1.680 dm3 at T = 255 K.
The van der Waals equation of state is (P + a(n/V )^2)(V/n − b) = RT,...
The van der Waals equation of state is (P + a(n/V )^2)(V/n − b) = RT, where a and b are gas-specific constants. For Hydrogen gas, a = 2.45 × 10^-2P a · m^6 and b = 26.61 × 10^-6m^3/mol, while for an ideal gas a = b = 0. (a) Consider trying to measure the ideal gas constant in a lab from the relation R = P V/(nT), where P, V, n, and T are all measured parameters. However,...
Problem 18.41 For oxygen gas, the van der Waals equation of state achieves its best fit...
Problem 18.41 For oxygen gas, the van der Waals equation of state achieves its best fit for a=0.14N⋅m4/mol2 and b=3.2×10−5m3/mol. Part A Determine the pressure in 1.7 mol of the gas at 9 ∘C if its volume is 0.50 L , calculated using the van der Waals equation. Express your answer using two significant figures. Part B Determine the pressure in 1.7 mol of the gas at 9 ∘C if its volume is 0.50 L , calculated using the ideal...
Use the van der Waals equation of state to calculate the pressure of 4.00 mol of...
Use the van der Waals equation of state to calculate the pressure of 4.00 mol of Xe at 483 K in a 4.20-L vessel. Van der Waals constants can be found here. Use the ideal gas equation to calculate the pressure under the same conditions.
4. Use the van der Waals gas law to derive a corrected equation for Gibbs free...
4. Use the van der Waals gas law to derive a corrected equation for Gibbs free energy.
Use the van der Waals equation of state to calculate the pressure of 2.90 mol of...
Use the van der Waals equation of state to calculate the pressure of 2.90 mol of CH4 at 457 K in a 4.50 L vessel. Van der Waals constants can be found here. P= ________ atm Use the ideal gas equation to calculate the pressure under the same conditions. P= ______ atm
A. Use the van der Waals equation to calculate the pressure exerted by 1.205 mol of...
A. Use the van der Waals equation to calculate the pressure exerted by 1.205 mol of Cl2 in a volume of 4.990 L at a temperature of 286.5 K . B. Use the ideal gas equation to calculate the pressure exerted by 1.205 mol of Cl2 in a volume of 4.990 L at a temperature of 286.5 K .
ADVERTISEMENT
Need Online Homework Help?

Get Answers For Free
Most questions answered within 1 hours.

Ask a Question
ADVERTISEMENT