A 0.200 M solution of a weak acid, HA, is 9.4% ionized. Using this information, calculate Ka for HA.
Answer – We are given, percent ionization = 9.4 % , [HA] = 0.200 M
We know formula for percent ionization,
Percent ionization = x/ initial concentration of HA *100 %
x = ionized species concentration = [H3O+]
So,
10 % = x / 0.200 * 100 %
x = 9.4 %*0.200 / 100 %
= 0.0188 M
X = [H3O+] = [HA-] = 0.0188 M
So, [HA] = 0.200 - 0.0188 M
= 0.181 M
We know,
Ka =[H3O+][HA-] / [HA]
= 0.0188 *0.0188 / 0.181
= 1.95*10-3
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