Consider the following unbalanced reaction. P4(s) + F2(g) PF3(g) How many grams of F2 are needed to produce 186 g of PF3 if the reaction has a 76.3% yield?
The balanced chemical reaction is:
P4(s) + 6F2(g) --> 4PF3(g)
actual mass = 186 g
use:
% yield = actual mass *100 / theoretical mass
76.3 = 186*100 / m
m = 243.8 g
Molar mass of PF3,
MM = 1*MM(P) + 3*MM(F)
= 1*30.97 + 3*19.0
= 87.97 g/mol
mass(PF3)= 243.8 g
number of mol of PF3,
n = mass of PF3/molar mass of PF3
=(243.8 g)/(87.97 g/mol)
= 2.771 mol
from balanced reaction,
moles of F2 required = (6/4)*moles of PF3 formed
= (6/4)*2.771 mole
= 4.16 moles
Molar mass of F2 = 38 g/mol
mass of F2,
m = number of mol * molar mass
= 4.16 mol * 38 g/mol
= 158 g
Answer: 158 g
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