the solubility of slaked lime, Ca(OH)2, in water is 0.185 g/100 mL. what volume of 0.00300 M HCl is needed to neutralize 13.0 mL of a saturated Ca(OH)2 solution?
mass of Ca(OH)2 = solubility x volume
so
mass of Ca(OH)2 present = 0.185 x 13 / 100
mass of Ca(OH)2 present = 0.02405
now
moles = mass / molar mass
so
moles of Ca(OH)2 = 0.02405 / 74
moles of Ca(OH)2 = 3.25 x 10-4
now
the reaction is
Ca(OH)2 + 2HCl --> CaCl2 + 2H20
we can see that
moles of HCl required = 2 x moles of Ca(OH)2
so
moles of HCl = 2 x 3.25 x 10-4
moles of HCl = 6.5 x 10-4
now
we know that
volume (ml) = moles x 1000 / molarity
so
volume of HCl (ml) = 6.5 x 10-4 x 1000 / 0.003
volume of HCl (ml) = 216.666
so
216.666 ml of HCl is required
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