i just need to know how to get H, I and J. thanks
guys
2 Ag+ + Cu --> Cu+2 + 2 Ag
You individually weigh out a piece of Copper Wire and an empty
Reaction Tube. You add a measured volume of silver nitrate solution
of known concentration to the Reaction Tube and drop in the copper
wire.
Weight of copper wire 1.3771 g
Weight of empty Reaction Tube 6.4591 g
Volume of AgNO3 solution used 3.65 mL
Molarity of original AgNO3 solution 0.1536 M
While the silver is being reduced, you make the following
spectroscopic measurements. The blank is distilled water. The
STANDARD is made by pipetting 1.00 ml of the original standard into
a cuvet and adding exactly 5.00 mL of ammonia + distilled water to
give a total volume in the cuvet of 6.00 mL.
%T of Blank 99.1 %
Concentration of original Cu Standard 0.0361 M
%T of Cu Standard in cuvet 39.0 %
After the reaction is complete, 2.35 ml of 14 M ammonia is added to
the Reaction Tube to give a total of 6.00 mL of blue solution. 1.00
mL is pipetted into the cuvet and 5.00 mL of ammonia and distilled
water were added. The %T of this mixed homogeneous solution was
measured in the spectrometer.
The mass of the remaining copper wire was measured
The precipitated silver metal in the Reaction Tube was washed with
distilled water and dried and the reaction tube with silver
crystals was weighed.
%T of Cu ion in Reaction Tube 24.8 %
Mass of Cu Wire after reaction 1.3579 g
Mass of dried Reaction Tube with Silver metal after reaction 6.5240
g
Calculate:
a) Mass of Silver Metal produced ______________ mg
b) Millimoles of Ag + used up ______________ mmol
c) Atomic Weight of Silver based on silver used up ______________
g/mol
d) Mass of Copper Metal lost from wire ______________ mg
e) Atomic Weight of Silver based on copper metal lost
______________ g/mol
f) Absorbance of Cu +2 standard ______________
g) Absorbance of Cu+2 in Reaction Tube ______________
h) Molarity of Cu+2 in Reaction Tube ______________ M
i) Millimole of Cu+2 in Reaction Tube ______________ mmol
j) Atomic Weight of Silver based on Cu+2 produced ______________
g/mol
h) Molarity of Cu+2 in Reaction Tube ______________ M
0.280mmol/6ml=0.046M
we can calculate molarity by use of absorbance
y=0.6055-0.4089= 0.1966
) Millimole of Cu+2 in Reaction Tube _0.030217_____________ mmol
Weight of copper wire 1.3771 g-Mass of Cu Wire after reaction 1.3579 g/63.54=0.0192/63.54=0.030217
moles of Cu = volume of AgNO3x molarity of Ag NO3/2=0.280 mmol
j) Atomic Weight of Silver based on Cu+2 produced ______________ g/mol
Ag produce A/C equation= 2x0.030217=0.6434mmol
At.wt = mass of silver produce/ mol=0.0649g/0.6434mmol=100.8g/mol
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