Question

i just need to know how to get H, I and J. thanks guys 2 Ag+...

i just need to know how to get H, I and J. thanks guys

2 Ag+ + Cu --> Cu+2 + 2 Ag
You individually weigh out a piece of Copper Wire and an empty Reaction Tube. You add a measured volume of silver nitrate solution of known concentration to the Reaction Tube and drop in the copper wire.
Weight of copper wire 1.3771 g
Weight of empty Reaction Tube 6.4591 g
Volume of AgNO3 solution used 3.65 mL
Molarity of original AgNO3 solution 0.1536 M
While the silver is being reduced, you make the following spectroscopic measurements. The blank is distilled water. The STANDARD is made by pipetting 1.00 ml of the original standard into a cuvet and adding exactly 5.00 mL of ammonia + distilled water to give a total volume in the cuvet of 6.00 mL.
%T of Blank 99.1 %
Concentration of original Cu Standard 0.0361 M
%T of Cu Standard in cuvet 39.0 %
After the reaction is complete, 2.35 ml of 14 M ammonia is added to the Reaction Tube to give a total of 6.00 mL of blue solution. 1.00 mL is pipetted into the cuvet and 5.00 mL of ammonia and distilled water were added. The %T of this mixed homogeneous solution was measured in the spectrometer.
The mass of the remaining copper wire was measured
The precipitated silver metal in the Reaction Tube was washed with distilled water and dried and the reaction tube with silver crystals was weighed.
%T of Cu ion in Reaction Tube 24.8 %
Mass of Cu Wire after reaction 1.3579 g
Mass of dried Reaction Tube with Silver metal after reaction 6.5240 g
Calculate:
a) Mass of Silver Metal produced ______________ mg
b) Millimoles of Ag + used up ______________ mmol
c) Atomic Weight of Silver based on silver used up ______________ g/mol
d) Mass of Copper Metal lost from wire ______________ mg
e) Atomic Weight of Silver based on copper metal lost ______________ g/mol
f) Absorbance of Cu +2 standard ______________
g) Absorbance of Cu+2 in Reaction Tube ______________
h) Molarity of Cu+2 in Reaction Tube ______________ M
i) Millimole of Cu+2 in Reaction Tube ______________ mmol
j) Atomic Weight of Silver based on Cu+2 produced ______________ g/mol

Homework Answers

Answer #1

h) Molarity of Cu+2 in Reaction Tube ______________ M

0.280mmol/6ml=0.046M

we can calculate molarity by use of absorbance

y=0.6055-0.4089= 0.1966

) Millimole of Cu+2 in Reaction Tube _0.030217_____________ mmol

Weight of copper wire 1.3771 g-Mass of Cu Wire after reaction 1.3579 g/63.54=0.0192/63.54=0.030217

moles of Cu = volume of AgNO3x molarity of Ag NO3/2=0.280 mmol

j) Atomic Weight of Silver based on Cu+2 produced ______________ g/mol

Ag produce A/C equation= 2x0.030217=0.6434mmol

At.wt = mass of silver produce/ mol=0.0649g/0.6434mmol=100.8g/mol

Know the answer?
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for?
Ask your own homework help question
Similar Questions
Problem: You weigh out a piece of copper wire (AW=63.546): Weight of copper standard....................0.2992 g Dissolve...
Problem: You weigh out a piece of copper wire (AW=63.546): Weight of copper standard....................0.2992 g Dissolve it in a slight excess of concentrated nitric acid. Add to the solution the required amount of concentrated ammonia. Transfer this quantitatively to a 100 mL volumetric flask, dilute to volume, and mix thoroughly. 10.00 mL of this is pipetted into a 100 mL volumetric flask, the required amount of concentrated ammonia is added and diluted to volume. This is Standard 1. Standard 2...
Procedure Reaction 1: Dissolving the Copper 1. Obtain a clean, dry, glass centrifuge tube. 2. Place...
Procedure Reaction 1: Dissolving the Copper 1. Obtain a clean, dry, glass centrifuge tube. 2. Place a piece of copper wire in a weighing paper, determine the mass of the wire and place it in the centrifuge tube. The copper wire should weigh less than 0.0200 grams. 3. In a fume hood, add seven drops of concentrated nitric acid to the reaction tube so that the copper metal dissolves completely. Describe your observations in the lab report. (Caution, Concentrated nitric...
A. You wish to prepare 198 grams of 10.3 % Na3PO4. How many grams will need...
A. You wish to prepare 198 grams of 10.3 % Na3PO4. How many grams will need of sodium phosphate and how many mL of water? Assume that the density of water is 1.00 g / ml. B. If 20.5 grams of an aqueous solution of cobalt(II) sulfate, CoSO4, contains 2.84 grams of cobalt(II) sulfate, what is the percentage by mass of cobalt(II) sulfate in the solution? C. An aqueous solution of lead nitrate, Pb(NO3)2, contains 8.74 grams of lead nitrate...
i just need work, 1. Calculate the Ksp for silver sulfite if the solubility in pure...
i just need work, 1. Calculate the Ksp for silver sulfite if the solubility in pure water is (2.2x10^-3) g/L. Answer :6.1 * 10^-16 2. What is the molar solubility of Mg(OH)2 in a basic solution with a pH of (1.32x10^1)? Ksp for Mg(OH)2 is (1.8x10^-12) Answer: 7.2x10^-11 3. A (1.6x10^2) mL sample of a solution that is (3.000x10^-3) M in AgNO3 is mixed with a (2.000x10^2) mL sample of a solution that is (2.00x10^-1) M in NaCN. After the...
Step 1) Cu (s) + 4 HNO3 -> Cu^(2+) + 2 NO3^(-) + 2 NO2 +...
Step 1) Cu (s) + 4 HNO3 -> Cu^(2+) + 2 NO3^(-) + 2 NO2 + 2 H2O Cu^(2+) + 6 H2O -> Cu(H2O)6 &^(2+) Description: Weight .49 of Cu wire and record . Under the heat add roughly 5 ML HNO3(nitric acid). When CU is dissolved add 10 mL of DI H2O. Step2) Cu(H2O)6 &^(2+) + 2 NaOH -> Cu(OH)3 + 6 H2O Description: Add 6 MNaOH drop wise while stirring. Stop when litmus paper turns blue. Step3) Cu(OH)3...
a)How is it possible to determine if CaCO3 is Cl- free after synthesis? b)How can the...
a)How is it possible to determine if CaCO3 is Cl- free after synthesis? b)How can the Cl- ions be remove from CaCO3 after synthesis? I should answer the questions from the following experiment but if you know the answer and you are sure, yo do not need to read experiment. Please answer correctly because i hav no chance to make wrong :(((( Physical and Chemical Properties of Pure Substances Objective The aim of today’s experiment is to learn handling chemicals...
I am doing a latenitelab on Molecular Mass by Freezing Poing Depression. I am stuck on...
I am doing a latenitelab on Molecular Mass by Freezing Poing Depression. I am stuck on three questions. 1.Suppose you added 4.000 g of FP sample #1 instead of 2.000 g, what would happen to the freezing point temperature of the water? 2. Suppose you dissolve 154.286 g of sodium chloride in 2.00 L of water. What is the molality of the solution given that the molar mass of sodium chloride is 58.44 g/mol and the density of water is...
1. A constant electric current flows for 3.35 h through electrolytic cells connected in series. One...
1. A constant electric current flows for 3.35 h through electrolytic cells connected in series. One contains a solution of AgNO3, and the second contains a solution of CuCl2. During this time, 1.80 g of silver is deposited in the first cell. (a) How many grams of copper are deposited in the second cell? g Cu (b) What is the current flowing in (in amperes) ?   A 2. Oxalic acid (H2C2O4) is present in many plants and vegetables. (a) Balance...
The formate ion, (CHO2-), is related to the acetate ion and forms ionic salts with many...
The formate ion, (CHO2-), is related to the acetate ion and forms ionic salts with many metal ions. Assume that 11.874 g of M(CHO2)2 (where M represents the atomic symbol for a particular metal) are dissolved in water. When a solution of 0.300 M sodium sulfate is added, a white precipitate forms. The sodium sulfate solution is added until no more precipitate forms, then a few excess milliliters are added. The precipitate is filtered, washed, and dried. It has a...
Ionic Compound Mass (g) T i (°C ) Tf (°C) ∆T (°C) q (J) ∆H (J/mol)...
Ionic Compound Mass (g) T i (°C ) Tf (°C) ∆T (°C) q (J) ∆H (J/mol) Calcium chloride 5g 22°C 34°C +12°C -251J Ammonium nitrate 5g 22°C 16°C -6°C +125J Magnesium Carbonate 2g 21°C 21°C 0°C 0 Sodium chloride 5g 21°C 20°C -1°C +21J Cs (water) = 4.18 J/g-°C 
, Density of water = 1g/mL 
 Q) Calculate: ∆H (J/mol), for the four ionic compounds? 1.      Were the results seen consistent with the solubility rules? If not, what is one possible...
ADVERTISEMENT
Need Online Homework Help?

Get Answers For Free
Most questions answered within 1 hours.

Ask a Question
ADVERTISEMENT