Question

6.(10 Pts.) Explain in some detail trans effect and trans influence. Use these ideas to explain...

6.(10 Pts.) Explain in some detail trans effect and trans influence. Use these ideas to explain why bubbling CO into a solution of [PtCl4]2- recovers exclusively cis-Pt(CO)2Cl2. How would you make the trans isomer?

Science   Chemistry   
0 0
Add a commentTranscribed image text
Next >

Homework Answers

Answer #1

The trans effect, which is often called the kinetic trans effect, refers to the observation that certain ligands increase the rate of ligand substitution when positioned trans to the departing ligand. Trans effect is kinetic effect.

The trans influence refers to the impact of a ligand on the length of the bond trans and other properties to it in the ground state of a complex. It is a thermodynamic effect.

CO has higher trans effect than Cl ligand.

cis-isomers do not form on bubbling CO into [PtCl4]2- because CO ligand with direct the second CO molecule trans to it and hence trans isomer is formed.

Starting [Pt(CO)4], cis isomers can be formed, Cl has less trans effect therefore second Cl have go trans to CO ligand.

0 0
Know the answer?
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Log In

Sign Up

Not the answer you're looking for?
Ask your own homework help question
Similar Questions
. Describe, in detail, a research question you could address using GenBank (2 pts.). Explain exactly...
. Describe, in detail, a research question you could address using GenBank (2 pts.). Explain exactly how you would use GenBank to answer your question. If you would need information beyond what is in GenBank, explain what information. If not, explain why not
6. What is short circuit evaluation? Give an example. 7. Briefly explain how operator precedence works...
6. What is short circuit evaluation? Give an example. 7. Briefly explain how operator precedence works in APL. 8. What does times do in Ruby? What about each? What about upto? Use code snippets to explain your answers. 9. What is a functional side effect? Give an example in code. 10. What is an unconditional branch statement? If you were to define a new language, would you include this construct? Why or why not?
6. (16 pts.) When you performed (or will perform) the atomic absorption experiment, you performed parallel...
6. (16 pts.) When you performed (or will perform) the atomic absorption experiment, you performed parallel dilutions (in lieu of serial dilutions) with a Zn2+ standardized solution, and used your analysis of these dilutions to construct a calibration curve relating the sensitivity of the instrument to the Zn2+ concentration In this problem, you are going to quantify the uncertainty in the concentrations of Zn2+ dilutions obtained from both serial and parallel dilutions and compare the results for the two methods....
Production Theory This chapter heavily concentrates on two key ideas. First, the idea that firms (and...
Production Theory This chapter heavily concentrates on two key ideas. First, the idea that firms (and individuals) should make decisions on how they optimize "on the margin" (where MC=MR).   Often people get confused and think about making decisions based on the average (such as average total cost).   Average total cost includes FIXED costs, which are sunk and shouldn't influence future decisions.   Second, the idea of diminishing marginal returns. That's the idea that each additional unit provides less...
Post lab question reguarding bomb calorimetry: Heat capacity for calorimeter: 10403.64 J/◦C Delta H TTCC: -6864.20...
Post lab question reguarding bomb calorimetry: Heat capacity for calorimeter: 10403.64 J/◦C Delta H TTCC: -6864.20 kJ/mol Resonance energy benzene: 423.01 kJ/mol ΔE = -7096.54kJ/mol 1. How does the bomb get sealed when it is charged with oxygen gas? 2. Why is 1 mL of water added to the bomb before the oxygen gas is added? Would one drop (0.05 mL) of water be satisfactory? 3. Is the mechanical energy of the stirrer included in the heat capacity of the...
1. Inflammation is generally a protective response, which would normally be beneficial. Is it an exclusively...
1. Inflammation is generally a protective response, which would normally be beneficial. Is it an exclusively beneficial response? Explain 2 pts 2. You are a physician and your patient has had a heart attack resulting in decreased blood flow to the heart tissue. Once blood flow is reestablished, what might be a major concern? 2pts 3. One of the first steps in inflammation is the development of increased adhesiveness of neutrophils to the endothelium cells of venules. How does this...
You design an experiment to test the effects of pesticides on size of radishes. You expect...
You design an experiment to test the effects of pesticides on size of radishes. You expect pesticides to have negative impacts on growth. You have been provided with 200 radish seeds and 40 growth pots. You have two treatment groups (P = pesticides, NP = no pesticides). [10 pts] a) Using the A to B relationship we have used since the start of class, what is your prediction? [2 pts] b) What type of dependent variable do you have? (circle...
Suppose the following data were obtained from the admissions office of a 2-year junior college. Of...
Suppose the following data were obtained from the admissions office of a 2-year junior college. Of the first-year class (F), 75% became sophomores (S) the next year and 25% dropped out (D). Of those who were sophomores during a particular year, 90% graduated (G) by the following year and 10% dropped out. (a) [8 pts] Set up a Markov chain transition matrix with states D, F, G, and S that describes the scenario. Hint: Although not explicitly stated, you can...
1. Vim commands: a. How do you auto indent your program? b. Explain what the following...
1. Vim commands: a. How do you auto indent your program? b. Explain what the following commands do: dd, y3, p, :set cindent (1 pt) VIM exercises These exercises on the computer need to be repeated by each student in the pair. This is to ensure that both students understand how to get around in Linux!!! For this part of the lab, you will create a .vimrc file that will help you develop your C++ programs using VIM. First, we...
Can i get the answer to these questions in detail explaining how you go to the...
Can i get the answer to these questions in detail explaining how you go to the solution 1.Convert to/from Hex (0) 2.Octal Binary Unsigned/ 2’s complement 3.Understand how to shift and rotate. 4.Understand the relationship between shifting and multiplication/division 5.Be able to recognize and use the following gates: AND OR NOT NAND NOR XOR 6.Understand how a half adder works Given a logical statement ((A OR B) AND NOT(C OR A)) show the gates. 7.What is the difference between an...
ADVERTISEMENT
Need Online Homework Help?

Get Answers For Free
Most questions answered within 1 hours.

Ask a Question
ADVERTISEMENT