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Application Questions:
12. Before using a solution of NaOH as a standard for a titration, its precise concentration must be determined by titration with a standard acid. This is because solid NaOH absorbs water from the atmosphere, so its solid form is difficult to keep free of contaminated H2O. A common acid used for standardization is the acid-salt, potassium hydrogen phthalate (KHP), KHC8H4O4. Another way is to use a standardized solution of sulfuric acid:
H2SO4(aq) + 2NaOH(aq) ® 2H2O(l) + Na2SO4(aq)
If 16.27 mL of 0.1125 M H2SO4 is required to titrate a 20.00 mL solution of NaOH, what is the molar concentration of the NaOH solution? Show your work.
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13. A student wanted to know the mass of vitamin C (ascorbic acid) in a vitamin C tablet. She dissolved the tablet in water and then titrated with 0.200 M NaOH. The balanced equation for the acid-base neutralization reaction is:
HC6H7O6(aq) + NaOH(aq) ® H2O(l) + NaC6H7O6(aq)
If 24.41 mL of NaOH was required to reach the endpoint, how many moles of ascorbic acid are in the tablet?You don’t need to show your work here.
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What is the mass of ascorbic acid in the tablet?(MM = 176.12 g/mol)
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Given that the student measured the mass of the vitamin C tablet as 4.601 g, calculate the percent-by-mass of ascorbic acid in the tablet.
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The reactiion is
2NaOH+ H2SO4----> Na2SO4+ 2H2O
It suggersts that two moles of NaOH is requuried to react with 1 mole sof H2SO4.
Moles of H2SO4= Molairty * Volume of H2SO4= (16.27/1000)*0.1125 =0.00183 moles
Hence,. moles of NaOH reqiored = 0.00183*2 = 0.003661
From moles= Molarity* Volume
0.003661 =Molarity* (20/1000)
Molairty =0.003661*1000/20=1.833305M
b)
as per the reaction, one mole of NaOH is required to neutralize 1 moles of Ascorbic acid
Moalirt of NaOH =0.2M
Volume consumed =24.41ml=24.41/1000 liters =0.02441liters
Moles of NaoH =0.2*0.02441=0.004882 gmoles
Hence, moles of ascorbic acid in the tablet = 0.004882 gmoles
Molecular weight of Ascorbic acid ( HC6H7O6) =1+ 6*12+1*7+6*16= 176
Moles = mass/ molecular weight=
Mass of ascorbic acid =Moles* Molecular weight =0.004882 *176 =0.8592 gms
Mas of the vitamin C = 4.601 gms
Mass % of ascorbic acid = (mas of ascorbic acid/ mass of vitamin)*100 =(0.8592/4.601)*100=18.67%
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