which of the following aqueous solutions has the largest molality of benzoic acid (c6h5cooh)
a) molallity = 4.5
b)
consider 100 g of water
moles = 100 / 18 = 5.556
molfraction of benzoic acid = moles of benzoic acid / ( moles of benzoic acid + water)
so
0.05 = y / (y + 5.556)
y = 0.29
so
molality = 0.29 x 1000 / 100
molality = 2.9
c) consider
1000 g of solution
mass of benzoic acid = 25 g
moles = 25 / 122 = 0.205
now
mass of water = 1000-25 = 975
so
molality = 0.205 x 1000 / 975
molality = 0.21
d)
moles = mass / molar mass
so
moles of benzoic acid = 3.2 / 122 = 0.02623
now
molality = 0.02623 x 1000 / 650
molality = 0.04
e)
mass = moles x molar mass
so
mass of water = 65 x 18 = 1170
now
molality = 1.5 x 1000 / 1170
molality = 1.282
so
answer is a) 4.5m C6H5COOH
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