Question

In question 3. the rate of disappearance of O2 was monitored. For the same balanced reaction...

In question 3. the rate of disappearance of O2 was monitored. For the same balanced reaction

O2 (aq) + 2 L-dopaH2 (aq) ⇌ 2 H2O + 2 L-dopaox

[O2] (mM) [L-dopaH2] (mM} rate loss of O2 (mMS-1)
4.2 1.7 1.2x!0-3
6.3 1.7 1.8x10-3
4.2 3.4 2.4x10-3
6.3 3.4 3.6x10-3

and the data from the first row from the table above, what are the expected rates of appearance or disappearance of each chemical?

a. O2 _______________________ b. L-dopa-H2 _________________ c. H2O ______________________ d. L-dopaox ___________________

Homework Answers

Answer #1

The reaction is,

O2 (aq) + 2 L-dopaH2 (aq) ⇌ 2 H2O + 2 L-dopaox

From the stoichiometric coefficients of the reactants and products, we can state the following relation between the rates of appearance or disappearance of each chemical

- d [O2] / dt = (1/2) x -d [L-dopaH2 ] / dt = (1/2) x d [H2O] / dt = (1/2) x d [L-dopaox ] / dt

Therefore,

Rate of dissapearance of O2 = - d [O2] / dt = 1.2 x 10^-3 mMS-1

Rate of dissapearance of L-dopaH2 = -d [L-dopaH2 ] / dt = 2 x 1.2 x 10^-3 = 2.4 x 10^-3 mMS-1

Rate of appearance of H2O = d [H2O] / dt = 2 x 1.2 x 10^-3 = 2.4 x 10^-3 mMS-1

Rate of appearance of L-dopaox = d [L-dopaox ] / dt = 2 x 1.2 x 10^-3 = 2.4 x 10^-3 mMS-1

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