A personal flotation device is being blown up through exhalation of breath, which is made up of roughly 78.0% N, 16.04% O2, 5.00% CO2, and .960% Ar. At STP, 10 breaths will cause the volume of the system to increase by 600mL. If the system is inflated with 65 breaths, how many moles of Oxygen will it contain? What volume in mL does the O2 occupy?
Solution:
1. Moles of O2 in 10 breaths:
10 breaths = 600 mL volume
O2 volume in 600 mL = 0.600 L x (16.04 / 100.00) = 0.0962 L
22.4 L is occupied by 1 mole O2. Therefore, 0.0962 L = (0.0962 L x 1 mol) / 22.2 L = 0.0042946 mole
2. Moles of O2 in 65 breaths:
10 breath = 0.0042946 mole O2
65 breath = x
x = (65 breath x 0.0042946 mole O2) / 10 breaths = 0.027924 mole O2.
Hence, 65 breaths will contain 0.027924 moles O2.
3. Volume of O2:
1 mole O2 = 22.4 L
0.027924 mole O2 = y
y= (22.4 L x 0.027924 mole O2) / 1 mole O2 = 0.625 L
1 L = 1000 mL
0.625 L = 0.625 L x (1000 mL / 1 L) = 625 mL
Hence, 625 mL is the volume of O2.
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