How many milligrams of sodium sulfide are needed to completely react with 25.00 mL of a 0.0100 M aqueous solution of cadmium nitrate, to form a precipitate of CdS(s)?
Solution :-
Balanced reaction equation
Cd(NO3)2 + Na2S ------ > CdS + 2 NaNO3
Using the mole ratio of the both reactant we can calculate the amount of Na2S needed to react with 25.00 ml of 0.0100 M Cd(NO3)2
Lets first calculate the moles of Cd(NO3)2
Moles = molarity * volume in liter
Moles of Cd(NO3)2 = 0.0100 mol per L * 0.025 L = 0.00025 mol Cd(NO3)2
Mole ratio is 1 : 1 so the moles of Na2S needed are same as moles of Cd(NO3)2
Soi moles of Na2S needed = 0.00025 moles
Now lets calculate its mass in milligram
(0.00025 mol Na2S * 78.0452 g / 1 mol )*(1000 mg / 1 g ) = 19.51 mg Na2S
So the mass of Na2S needed is 19.51 mg Na2S
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