2) Norepinephrine is a hormone released during stress. It is composed of carbon, hydrogen, oxygen, and nitrogen. The percent composition is 56.8% C, 6.56% H, 28.4% O, and 8.28% N. Find the empirical formula for norepinephrine.
Assume a basis of
m = 100 g of sample
then
56.8 g C
6.56 g of H
28.4 g of O
8.28 g of N
change all mass to mole
MW C = 12 g/mol
MW H = 1 g/mol
MW N = 14 g/mol
MW O = 16 g/mol
then
n C = m/MW = 56.8/12 = 4.7333
n H = m/MW = 6.56/1 = 6.56
n O = m/MW = 28.4/16 = 1.775
n N = m/MW = 8.28/14 = 0.591428
choose the smalles as basis, that is N
N:C = 4.7333/0.5914 = 8
N:H = 6.56/0.5914 = 11.08
N:O = 1.775/0.5914 = 3.00135
therefore, for a N = 1
we have
C8H11O3N1
or simply
C8H11O3N
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