Question

Menthol is a crystalline substance with a peppermint taste and odor. When 0.990 g of menthol...

Menthol is a crystalline substance with a peppermint taste and odor. When 0.990 g of menthol is dissolved in 25.0 g of cyclohexane, the freezing point of the solution is lowered by 5.28 °C. The freezing point and Kf constant for cyclohexane can be found here. Calculate the molar mass of menthol in g/mol.

Homework Answers

Answer #1

Dear Friend your answer is

  1. Step 1: Calculate the freezing point depression of the solution.

    Tf = (Freezing point of pure solvent) - (Freezing point of solution)
    (20.1 oC) - (5.28 oC) = 14.73 oC
  2. Step 2 : Calculate the molal concentration of the solution using the freezing point depression.

    Tf = (Kf) (m)
    m = (14.73 oC) / (6.5 oC/molal)
    m = 2.2661 molal
  3. Step 3: Calculate the molar mass of the unknown using the molal concentration.

    m = 2.2661 molal = 2.2661 mol menthol / kg cyclohexane

    moles menthol = (2.2661 mol menthol / kg cyclohexane) (0.099 kg cyclohexane) = 2.2889 X 10-3 mol menthol

    molar mass of menthol = (0.99 g menthol) / (2.2889 X 10-3 mol menthol)

    molar mass of menthol = 432.5221 g/mol

Thank you, all the best.

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