Question

Compound A, C8H10, undergoes nitration to give 2 products. The 1H NMR spectrum of A shows...

Compound A, C8H10, undergoes nitration to give 2 products. The 1H NMR spectrum of A shows a complex five-proton multiplet at 7.27-7.40 δ, a two-proton quartet at 2.60 δ, and a three-proton triplet at 1.25 δ. What is the structure of A?

Homework Answers

Answer #1

According to the given spectrum datas, the compound A contains a six-membered carbon ring where 1 proton is substituted with a group (-CH2CH3) (an activating group) . The most obvious signals for rest of the five protons in this spectrum is the splitting into multiplets and the signals emitted by the -CH3 proton is triplet at 1.25ppm and the signal from the -CH2 proton is a quartet at 2.60ppm.

Regarding to the reaction of nitration, you get a mixture of mainly 2 isomers : 2- nitroethylbenzene and 4- nitroethylbenzene , As Ethyl groups are said to be 2,4-directing.

Thus, the structure of compound A must be the Ethylbenzene.

Know the answer?
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for?
Ask your own homework help question
Similar Questions
Draw a compound that is consistent with the following 1H NMR data: C4H9Br, has 3 signals...
Draw a compound that is consistent with the following 1H NMR data: C4H9Br, has 3 signals in the 1H NMR spectrum, 2 doublets and a 9-line multiplet. C4H8Br2, has 3 signals in 1H NMR spectrum, a singlet, a triplet and a quartet  
The 1H NMR spectrum of a compound with the formula C4H8Cl2 consists of a triplet at...
The 1H NMR spectrum of a compound with the formula C4H8Cl2 consists of a triplet at δ 3.6 ppm and a triplet at 1.9 ppm in the ratio of 1:1. What compound is consistent with this spectrum
Propose the structure of a compound that exhibits the following 1H NMR data. (1) C5H10O 1.09...
Propose the structure of a compound that exhibits the following 1H NMR data. (1) C5H10O 1.09 δ (6H, doublet) 2.12 δ (3H, singlet) 2.58 δ (1H, septet) (2) C5H12O       0.91 δ (3H, triplet)       1.19 δ (6H, singlet)       1.50 δ (2H, quartet)       2.24 δ (1H, singlet) (3) C4H10O       0.90 δ (6H, doublet)       1.76 δ (1H, multiplet)       3.38 δ (2H, doublet)       3.92 δ (1H, singlet) (4) C4H8O2       1.21 δ (6H, doublet)       2.59 δ (1H, septet)       11.38 δ (1H, singlet)
Compound F, C5H8O, has an 1H-NMR spectrum that exhibits absorption in the alkane region (1 to...
Compound F, C5H8O, has an 1H-NMR spectrum that exhibits absorption in the alkane region (1 to 2 δ) and shows a triplet at 2.8 δ. Treatment of F, first with aqueous acid and then with KMnO4, yields pentanedioic acid. (KMnO4 cleaves 1,2-diols to yield carboxylic acids.) Propose a structure for compound F.
A compound, C9H12, shows an IR peak at 750 cm-1. Its 1H NMR spectrum has peaks...
A compound, C9H12, shows an IR peak at 750 cm-1. Its 1H NMR spectrum has peaks at delta 7.1 (4 H, broad singlet), 2.6 (2 H, quartet, J=8 Hz), 2.3 (3 H, singlet), and 1.2 (3 H, triplet, J=8 Hz). Draw its structure in the window below.
A compound, C10H14, shows an IR peak at 745 cm-1. Its 1H NMR spectrum has peaks...
A compound, C10H14, shows an IR peak at 745 cm-1. Its 1H NMR spectrum has peaks at delta 7.18 (4 H, broad singlet), 2.70 (4 H, quartet, J=7 Hz), and 1.20 (6 H, triplet, J=7 Hz). Draw its structure in the window below. You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. In cases where there is more than one answer, just draw one.
A compound, C14H12, shows IR peaks at 700, 740,and 890 cm-1. Its 1H NMR spectrum has...
A compound, C14H12, shows IR peaks at 700, 740,and 890 cm-1. Its 1H NMR spectrum has peaks at delta 7.3 (10 H, broad singlet) and 5.4 (2 H, singlet). Draw its structure in the window below.
Draw the structure of the compound C3H6Cl2 from its proton (1H) NMR spectrum below. First-order spin-spin...
Draw the structure of the compound C3H6Cl2 from its proton (1H) NMR spectrum below. First-order spin-spin splitting rules and equal coupling constants can be assumed. (Detailed analysis of any non-first order portions of the spectrum will not be required.) Integral ratios to the nearest whole number are (left to right) 1:2:3
(3 pts) In the mass spectrum on page 3, what name do we give the peak...
(3 pts) In the mass spectrum on page 3, what name do we give the peak at 150 m/z units? (1) base peak     (2) molecular ion     (3) molecular fragment       (4) baseline (3 pts) In the mass spectrum on page 3, what name do we give the peak at 135 m/z units? (1) base peak     (2) molecular ion     (3) molecular fragment       (4) baseline (3 pts) The absorbances present in an IR spectrum result from: (1) “spin flipping” of nuclei     (2) fragmentation...
Give the three products of pyruvate oxidation: 2. The compound that functions as the major carrier...
Give the three products of pyruvate oxidation: 2. The compound that functions as the major carrier of electrons from complex I to complex III of the electron transport chain is ___________________________________________________. 3.______________________________ is the name of the enzyme that eliminates or "scavenges" highly reactive oxygen species like O2- , a reactive oxygen species, that can damage DNA or other molecules in the cell. 4.In the electron transport chain, the final electron acceptor, which is    , is reduced to    . 5.The side chain...
ADVERTISEMENT
Need Online Homework Help?

Get Answers For Free
Most questions answered within 1 hours.

Ask a Question
ADVERTISEMENT