Consider the reaction X ---> Y in a cell at 37 degrees Celcius. At equilibrium, the concentrations of X and Y are 50 micrometers and 5 micrometers, respectively. Use this information and your knowledge of the relationships between deltaG, and deltaGo , and the equilibrium constant (K) to answer questions a-c.
a) What is the value of K for this reaction?
b) What is the value of the standard free energy? is the reaction X-->Y and energetically favorable or unfavorable reaction under standard conditions?
c) Imagine circumstances in which the concentration of X is 1000 micrometers and that of Y is 1 micrometer. Is conversion of X to Y favorable? Will it happen quickly?
a) What is the value of K for this reaction?
equilibrium constant K = [Y] / [X] = 5 / 50 = 0.1
b)
deltaGo = - R T ln K
= - 8.314 x 10^-3 x 310 x ln 0.1
= 5.93 kJ
the reaction X-->Y is unfavorable reaction under standard conditions. because delta Go is positive.
(c)
equilibrium constant K = [Y] / [X] = 1 / 1000 = 0.001
no. it is unfavourable. because K value is less than 1
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