Question

Methyl salicylate (oil of wintergreen) is prepared by heating salicylic acid (C7H6O3) with methanol (CH3OH) C7H6O3...

Methyl salicylate (oil of wintergreen) is prepared by heating salicylic acid (C7H6O3) with methanol

(CH3OH) C7H6O3 + CH3OH--> C8H8O3 + H2O

What is the percent yield if reaction of 5.172 g of salicylic acid with an excess of methanol produced a measured yield of 3.733 g of oil of wintergreen?

Homework Answers

Answer #1


Molar mass of C7H6O3,
MM = 7*MM(C) + 6*MM(H) + 3*MM(O)
= 7*12.01 + 6*1.008 + 3*16.0
= 138.118 g/mol

mass of C7H6O3 = 5.172 g
mol of C7H6O3 = (mass)/(molar mass)
= 5.172/138.118
= 0.0374 mol



According to balanced equation
mol of C8H8O3 formed = moles of C7H6O3
= 0.0374 mol


Molar mass of C8H8O3,
MM = 8*MM(C) + 8*MM(H) + 3*MM(O)
= 8*12.01 + 8*1.008 + 3*16.0
= 152.144 g/mol


mass of C8H8O3 = number of mol * molar mass
= 0.0374*152.144
= 5.6972 g

% yield = actual mass*100/theoretical mass
= 3.733*100/5.6972
= 65.5 %
Answer: 65.5 %

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