Use group theory to construct a qualitative molecular orbital diagram for the hypothetical square planer silane molecule(SiH4) ignore d orbital interaction
determine the bond order and identify the HUMO and LUMO
*Then compare your result to the MOdigram for CH4 (tetrahedral)
Discuss your conclusions
The qualitative molecular orbital diagram for the hypothetical square planar silane molecule(SiH4) can be drawn as shown below.
The bond order of SiH4 = (1/2) * 8 = 4 (since there are a total of 8 electrons)
The bond order of Si-H = 4/4 = 1 (since there are 4 H's)
Here, t2-level is the HOMO and t2* level is the LUMO.
The MO diagram for methane molecule (CH4) can be drawn as shown below.
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