Consider the following half-reactions:
Ag+ (aq) + e- --> Ag(s)
E cell = 0.80 VV
Cu2+(aq) + 2e- --> Cu(s)
E cell = 0.34 V
Pb2+(aq) + 2e- --> Pb(s)
E cell = -0.13 V
Fe2+(aq) + 2e- --> Fe(s)
E cell = -0.44 V
Al3+ (aq) + 3e- --> Al(s)
E cell = -1.66 V
Which of the above metals or metal ions will oxidize Pb(s)?
a. Ag+(aq) and Cu2_(aq)
b. Ag(s) and Cu(s)
c. Fe2+(aq) and Al3+(aq)
d. Fe(s) and Al(s)
e. Cu2+(aq) and Fe2+(aq)
Answer : option a) Ag+(aq) and Cu2+(aq)
Explanation :
Ag+ (aq) + e- --> Ag(s) E cell = 0.80 VV
Cu2+(aq) + 2e- --> Cu(s) E cell = 0.34 V
Pb2+(aq) + 2e- --> Pb(s) E cell = -0.13 V
Fe2+(aq) + 2e- --> Fe(s) E cell = -0.44 V
Al3+ (aq) + 3e- --> Al(s) E cell = -1.66 V
Pb(s) will be oxidized , when the reduction potential of the metals greater than the reduction potential of Pb(s).
here Ag+ and Cu2+ have greater reduction potential than Pb. so these two are oxidize Pb(s)
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