For which one of the following reactions will the enthalpy change be approximately equal to the internal energy change ?
2 H2(g) + O2(g) → 2 H2O(ℓ)
H2O(ℓ) → H2O(g)
CaCO3(s) → CaO(s) + CO2(g)
H2(g) + Br2(g) → 2 HBr(aq)
CH4(g) + 2 O2(g) → CO2(g) + 2 H2O(g)
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