Question

REACTION A + B + C ---> Products Trial [A](M) [B](M) [C](M) Rate(M/s) 1 1.0 1.0...

REACTION A + B + C ---> Products

Trial [A](M) [B](M) [C](M) Rate(M/s)
1 1.0 1.0 0.010 1.0E-4
2 1.0 2.0 0.010 4.0E-4
3 1.0 1.0 0.020 2.0E-4
4 2.0 1.0 0.010 2.0E-4

Using the data in the table and the rate law below, identify the reaction order with respect to each reactant.

Rate = k[A]m[B]n[C]p

(I need to find m=?, n=?, and p=?)

Homework Answers

Answer #1

let the rate be r= K[A] a[ B]b [C]c , where a , b, and c are orders of reaction with respect to A, B and C. K is rate constant

from 1st data point, 1*10-4= K[1]a [1]b [ 0.01]c (1)

from 2nd data point , 4*10-4 =K[1]a[2]b[0.01]c (2) Eq.2/Eq.1 gvies 4= 2b, b= 2

from 3rd data point, 2*10-4= K[1]a [1]b[ 0.02]c (3), Eq.3/Eq.1 gives 2c= 2, c=1

from 4th data point, 2*10-4 = K[2]a [1]b[0.01]c (4), Eq.4/Eq.1 , 2a=2, a=1

from Eq.1, 1*10-4= K[ 1]1[1]2 [0.01]1, K= 0.01

the rate equation becomes r= 0.01[A] [B]2 [C]

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