A tanker truck carrying 6.05×103 kg of concentrated sulfuric acid
solution tips over and spills its load.
The sulfuric acid solution is 95.0% H2SO4 by mass and
has a density of 1.84 g/mL .
Sodium carbonate (Na2O3 ) is used to neutralize the sulfuric acid
spill. How many kilograms of sodium carbonate must be added to
neutralize 6.05×103 kg of sulfuric acid solution?
Given that;
6.05×10^3 kg of concentrated sulfuric acid
The sulfuric acid solution is 95.0% H2SO4 by mass
and has a density of 1.84 g/mL .
First calculate the mass of H2SO4 as follows:
6.05×10^3 kg = 6.05×10^6 g
1.00 kg = 1000 g
m(H2SO4) = %H2SO4 x m(solution)
m(H2SO4) = 0.95 x 6.05×10^6 g
m(H2SO4) = 5.748x10^6 g of H2SO4
Now calculate the number of mole of H2SO4:
Number of moles = amount in g / molar mass
=5.748x10^6 g of H2SO4 / 98.078 g/ mole
= 58601 mol of H2SO4
the balance reaction between H2SO4 and Na2CO3 is as follows:
H2SO4 + Na2CO3 = Na2SO4 + CO2 + H2O
then calculate the mole of Na2CO3:
= 58601 mol of H2SO4 *1/1
= 58601 mol of Na2CO3
Amount in g = number of moles * molar mass
=58601 mol of Na2CO3 *105.99 g/ mole
= 621115.623 g
= 6211.15 kg
= 6.21*10^3 kg of Na2CO3
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