Determine the pH of each solution : a) 3.1 X 10 ^-2 M HI b). 0.116 M HClO4 c). a solution that is 5.6×10−2 M in HClO4 and 2.8×10−2 M in HCl d). a solution that is 1.85% HCl by mass (Assume a density of 1.01 g/mL for the solution.)
: a) 3.1 X 10 ^-2 M HI
pH = -log(H) = -log(3.1*10^-2) = 1.50863
b). 0.116 M HClO4
pH = -lG(H+) = -log(0.116) = 0.93554
c). a solution that is 5.6×10−2 M in HClO4 and 2.8×10−2 M in HCl
H+ = 5.6*10^-2 + 2.8*10^-2 = 0.084 M
pH = -log(H) = -log(0.084) = 1.07572
d). a solution that is 1.85% HCl by mass (Assume a density of 1.01 g/mL for the solution.)
assume
m = 100 g in total so
m = 1.85 g ar eHCl
mol = mass/MW = 1.85/36 = 0.05138 mol
mass of water = 100-1.85 = 98.15 g of water
assume D= 1 g /ml then V = 98.15 ml
threfore
M = mol/V = 0.05138/(98.15 /1000) = 0.52348
pH = -log(H) = -log(0.52348) = 0.28109
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