Question

Large quantities of hydrogen are needed for the synthesis of ammonia. One preparation of hydrogen involves...

Large quantities of hydrogen are needed for the synthesis of ammonia. One preparation of hydrogen involves the reaction between carbon monoxide and steam at 3.00 × 102 °C in the presence of a copper-zinc catalyst:

CO(g) + H2O(g) ⇆ CO2(g) + H2(g)

Using the standard formation constant data in the table, calculate the equilibrium constant (KP) for the reaction at 3.00 × 102 °C and the temperature at which the reaction favors the formation of CO and H2O

Species

Δ

H

o

f

(kJ/mol)

Δ

S

o

(J/mol

·

K)

CO(g)

−110.5 197.7

H2O(g)

−241.8 188.8

CO2(g)

−393.5 213.8

H2(g)

0 130.7


KP =

T = K

Will a larger KP be attained at the same temperature if a more efficient catalyst is used?

  

yes

  

no

That cannot be known.

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