Large quantities of hydrogen are needed for the synthesis of ammonia. One preparation of hydrogen involves the reaction between carbon monoxide and steam at 3.00 × 102 °C in the presence of a copper-zinc catalyst:
CO(g) + H2O(g) ⇆
CO2(g) + H2(g)
Using the standard formation constant data in the table, calculate
the equilibrium constant (KP) for the
reaction at 3.00 × 102 °C and the temperature at which
the reaction favors the formation of CO and H2O
Species |
Δ H
(kJ/mol) |
Δ S
· K) |
||||||
CO(g) |
−110.5 | 197.7 | ||||||
H2O(g) |
−241.8 | 188.8 | ||||||
CO2(g) |
−393.5 | 213.8 | ||||||
H2(g) |
0 | 130.7 |
KP =
T = K
Will a larger KP be attained at the
same temperature if a more efficient catalyst is used?
yes |
|
no |
|
That cannot be known. |
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